Thanks for the link Rus, that’s a good explanation but it stops before it’s done.
For Steve and others:
As explained, in a turn, the front wheels travel further and need to turn faster than the rear ones. This means that the front driveshaft has to turn faster than the rear one. This is no problem in 2WD as the two driveshafts are not connected to each other, only the rear is driving, and either one can turn faster or slower than the other one. But in 4WD the two driveshafts are connected together in the transfer case and must turn at the same speed. So the faster shaft is trying to turn the slower shaft at its own, faster, rate. Steel is not rubber, but it does have some “stretch/rebound” in it. If you can imagine a rubber driveshaft, you would see how both of them would be twisted. And not only the driveshafts but the drive gears, differential gears, axle shafts, hubs, wheels and tires are all subjected to this force. On slick surfaces, the tires can slip and relieve that stress. On dry hard surfaces (pavement), it’s harder for them to slip, maybe to the point that something else has to give. All it takes is for one wheel, any wheel, to slip to relieve it.
As to the transfer case, the only parts involved are the two output shafts and the sliding coupler that connects them in 4WD. With one shaft trying very hard to turn the other, the coupler has a lot of pressure on it, and that’s why it’s hard to shift out of 4WD. None of the gear train in either the transfer case or the transmission are involved.
Sorry about the long post, but I hope it helped.
BW