This is what happened to me....When I had my engine machined about 9 years ago, the machine shop didnt replace the valve guildes, instead they reamed out the old guides and pressed in a brass sleeve. (Why I dont know, and I didnt catch on)The result was that after a few hundred miles, the sleeves would gall and the valves would hang open for a little bit, then they would cool down and start closing. It drove me crazy troubleshooting. By the time it was figured out, a few years and a lot of head gaskets later, it was too late to go kick a machinist's backside, so I replaced them with the valve guides from a another engine.
It takes a lot of force to pull the old guides out, I used grade 8 bolts in progressively shorter lengths (all thread is way too soft) and a socket on top of the block to get them out, a machinist friend of mine made a tool to drive the guides back in without damaging them. It is pictures below. I put a locking collar on the tool that would stop at the top of the block to insure I drove the "new" ones to the proper depth.
